Guide to Sodium Hexametaphosphate Safety and Compliance

November 12, 2025
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Imagine a food processing plant evaluating the use of sodium hexametaphosphate to enhance product water retention and texture. While pursuing technical benefits, potential safety risks and compliance requirements remain critical considerations that could lead to serious production incidents or legal disputes if overlooked. This analysis examines the Safety Data Sheet (SDS) for sodium hexametaphosphate to provide a complete understanding of its properties, hazards, emergency procedures, and compliance strategies.

1. Product Identification and Supplier Information: Ensuring Traceability

The SDS clearly identifies the product as sodium hexametaphosphate (CAS 68915-31-1), manufactured by Aldrich and supplied by Sigma-Aldrich Israel Ltd. with complete contact details. While the REACH registration number isn't provided due to exemption or tonnage requirements, this information ensures quick access to technical support during emergencies.

  • Product Identification: The CAS number serves as a unique chemical identifier.
  • Supplier Accountability: Detailed supplier information enables quality tracing and accident liability determination.
2. Hazard Identification: Foundation for Risk Assessment

According to EU Regulation (EC) No. 1272/2008, sodium hexametaphosphate isn't classified as hazardous. The SDS confirms it contains no persistent, bioaccumulative, and toxic (PBT) components nor endocrine disruptors.

  • Regulatory Compliance: Meets EU safety standards.
  • Environmental Safety: No long-term environmental risks from PBT/vPvB substances.
3. Composition: Understanding Material Content

The product contains sodium hexametaphosphate (also known as Calgon or polyphosphate glass) without additional concerning components, as confirmed by applicable regulations.

4. First Aid Measures: Emergency Response Protocol

The SDS provides specific first aid instructions:

  • Inhalation: Move to fresh air immediately
  • Skin Contact: Remove contaminated clothing and rinse with water
  • Eye Contact: Flush with plenty of water and remove contact lenses
  • Ingestion: Drink water and consult a physician
5. Firefighting Measures

While non-flammable, sodium hexametaphosphate may release harmful gases in fire conditions. Firefighters should prevent water runoff contamination.

6. Accidental Release Measures

For spills:

  • Prevent dust inhalation
  • Block drainage systems
  • Collect and contain spillage using dry methods
  • Thoroughly clean affected areas
7. Handling and Storage

Store in dry, sealed containers. Classified as non-flammable solid (TRGS 510:13).

8. Exposure Controls and Personal Protection

Recommended protective equipment:

  • NIOSH/EN 166 certified eye protection
  • CE-certified gloves (e.g., Dermatril® L)
  • P1 respirators in dusty environments
9. Physical and Chemical Properties

Key characteristics:

  • Physical state: Crystalline solid
  • Melting point: 628°C
  • Water solubility: High
  • Flammability: None
10. Stability and Reactivity

Chemically stable under normal conditions. Avoid strong oxidizers. May produce hazardous decomposition products in fires.

11. Toxicological Information

Toxicity data:

  • Oral LD50 (rat): 3,053 mg/kg
  • Dermal LD50 (rabbit): >7,940 mg/kg
  • Mild eye and skin irritation
12. Ecological Information

No significant environmental hazards identified. Not classified as PBT/vPvB or endocrine disruptor.

13. Disposal Considerations

Follow applicable waste regulations.

14. Transport Information

Not classified as dangerous goods for transport.

15. Regulatory Information

Complies with EU Regulation (EC) No. 1907/2006 (REACH). No chemical safety assessment conducted.

Conclusion

This comprehensive analysis of sodium hexametaphosphate's SDS provides essential information for safe industrial application. Understanding these safety parameters enables proper risk management while maintaining compliance with environmental and workplace safety standards.